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Cu(In 4

Ga)Se2 3

光催化 3

CCS 2

CO2利用 2

CO2封存 2

CO2捕集 2

二氧化碳 2

低温SOFC 2

低碳发展 2

催化剂 2

固体氧化物电解池 2

大气温度 2

温度 2

温度分布 2

温度控制 2

碳中和 2

高温气冷堆 2

&alpha 1

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Design and analysis of electrothermal metasurfaces

Xiu LIU, Zhuo LI, Zexiao WANG, Hyeong Seok YUN, Sheng SHEN

《能源前沿（英文）》 2023年 第17卷 第1期   页码 134-140 doi: 10.1007/s11708-022-0841-9

摘要： Electrothermal metasurfaces have garnered considerable attention owing to their ability to dynamically control thermal infrared radiation. Although previous studies were mainly focused on metasurfaces with infinite unit cells, in practice, the finite-size effect can be a critical design factor for developing thermal metasurfaces with fast response and broad temperature uniformity. Here, we study the thermal metasurfaces consisting of gold nanorods with a finite array size, which can achieve a resonance close to that of the infinite case with only several periods. More importantly, such a small footprint due to the finite array size yields response time down to a nanosecond level. Furthermore, the number of the unit cells in the direction perpendicular to the axis of nanorods is found to be insensitive to the resonance and response time; thus, providing a tunable aspect ratio that can boost the temperature uniformity in the sub-Kelvin level.

关键词： modulated thermal infrared radiation     metasurface     nanosecond response time     sub-Kelvin temperature uniformity     finite size     aspect ratio    

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CeO doping boosted low-temperature NH-SCR activity of FeTiO catalyst: A microstructure analysis and reaction

《环境科学与工程前沿（英文）》 2022年 第16卷 第5期 doi: 10.1007/s11783-022-1539-2

摘要：

• CeO2 doping significantly improved low-temperature NH3-SCR activity on FeTiOx.

关键词： NH3-SCR     CeO2 doping     Low-temperature NOx removal     Improved redox property     In situ XAFS analysis    

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Modeling and optimization of an enhanced battery thermal management system in electric vehicles

Mao LI, Yuanzhi LIU, Xiaobang WANG, Jie ZHANG

《机械工程前沿（英文）》 2019年 第14卷 第1期   页码 65-75 doi: 10.1007/s11465-018-0520-z

摘要： This paper models and optimizes an air-based battery thermal management system (BTMS) in a battery module with 36 battery lithium-ion cells. A design of experiments is performed to study the effects of three key parameters (i.e., mass flow rate of cooling air, heat flux from the battery cell to the cooling air, and passage spacing size) on the battery thermal performance. Three metrics are used to evaluate the BTMS thermal performance, including (i) the maximum temperature in the battery module, (ii) the temperature uniformity in the battery module, and (iii) the pressure drop. It is found that (i) increasing the total mass flow rate may result in a more non-uniform distribution of the passage mass flow rate among passages, and (ii) a large passage spacing size may worsen the temperature uniformity on the battery walls. Optimization is also performed to optimize the passage spacing size. Results show that the maximum temperature difference of the cooling air in passages is reduced from 23.9 to 2.1 K by 91.2%, and the maximum temperature difference among the battery cells is reduced from 25.7 to 6.4 K by 75.1%.

关键词： thermal management     electric vehicle     lithium-ion battery     temperature uniformity     design optimization    

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Cu-modified active carbon fiber significantly promoted HS and PH simultaneous removal at a low reaction temperature

《环境科学与工程前沿（英文）》 2021年 第15卷 第6期 doi: 10.1007/s11783-021-1425-3

摘要：

• Cu0.15-ACF performs the best for H2S and PH3 simultaneous removal.

关键词： ACF     H2S     PH3     Cu     Low temperature     Simultaneous removal    

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Preparation of Cu/ZnO/Al

Hui FAN, Huayan ZHENG, Zhong LI

《化学科学与工程前沿（英文）》 2010年 第4卷 第4期   页码 445-451 doi: 10.1007/s11705-010-0521-x

摘要： Cu/ZnO/Al O catalysts with Cu/Zn/Al ratios of 6/3/1 were precipitated and aged by conventional and microwave heating methods and tested in the slurry phase reactor for methanol synthesis. The effect of technological condition of precipitation and aging process under microwave irradiation on the catalytic performance was investigated to optimize the preparing condition of Cu/ZnO/Al O catalyst. The results showed that the microwave irradiation during precipitation process could improve the activity of the catalyst, but had little effect on the stability. While the microwave irradiation during aging process has a great benefit to both the activity and stability of the catalyst, the catalyst aged at 80°C for 1 h under microwave irradiation possessed higher methanol space time yield (STY) and more stable catalytic activity. The activity and stability of the catalyst was further enhanced when microwave irradiation was used in both precipitation and aging processes; the optimized condition for the catalyst precursor preparation was precipitation at 60°C and aging at 80°C under microwave irradiation.

关键词： microwave irradiation     precipitation temperature     aging temperature     methanol synthesis     Cu/ZnO/Al2O3 catalyst    

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Denitrification performance and sulfur resistance mechanism of Sm–Mn catalyst for low temperature NH-SCR

《化学科学与工程前沿（英文）》 2023年 第17卷 第5期   页码 617-633 doi: 10.1007/s11705-022-2258-8

摘要： MnOx and Sm–Mn catalysts were prepared with the coprecipitation method, and they showed excellent activities and sulfur resistances for the selective catalytic reduction of NOx by NH3 between 50 and 300 °C in the presence of excess oxygen. 0.10Sm–Mn catalyst indicated better catalytic activity and sulfur resistance. Additionally, the Sm doping led to multi-aspect impacts on the phases, morphology structures, gas adsorption, reactions process, and specific surface areas. Therefore, it significantly enhances the NO conversion, N2 selectivity, and sulfur resistance. Based on various experimental characterization results, the reaction mechanism of catalysts and the effect of SO2 on the reaction process about the catalysts were extensively explored. For 0.10Sm–Mn catalyst, manganese sulfate and sulfur ammonium cannot be generated broadly under the influence of SO2 and the amount of surface adsorbed oxygen. The Bronsted acid sites strengthen significantly due to the addition of SO2, enhancing the sulfur resistance of the 0.10Sm–Mn catalyst.

关键词： MnOx     Sm–Mn     catalyst     NH3-SCR     sulfur resistance    

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Wide gap active brazing of ceramic-to-metal-joints for high temperature applications

K. Bobzin,L. Zhao,N. Kopp,S. Samadian Anavar

《机械工程前沿（英文）》 2014年 第9卷 第1期   页码 71-74 doi: 10.1007/s11465-014-0291-0

摘要：

Applications like solid oxide fuel cells and sensors increasingly demand the possibility to braze ceramics to metals with a good resistance to high temperatures and oxidative atmospheres. Commonly used silver based active filler metals cannot fulfill these requirements, if application temperatures higher than 600°C occur. Au and Pd based active fillers are too expensive for many fields of use. As one possible solution nickel based active fillers were developed. Due to the high brazing temperatures and the low ductility of nickel based filler metals, the modification of standard nickel based filler metals were necessary to meet the requirements of above mentioned applications. To reduce thermally induced stresses wide brazing gaps and the addition of Al2O3 and WC particles to the filler metal were applied. In this study, the microstructure of the brazed joints and the thermo-chemical reactions between filler metal, active elements and WC particles were analyzed to understand the mechanism of the so called wide gap active brazing process. With regard to the behavior in typical application oxidation and thermal cycle tests were conducted as well as tensile tests.

关键词： wide gap     active brazing     nickel filler metals     high temperature application     WC     Al2O3    

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Effect of heat transfer space non-uniformity of combustion chamber components on in-cylinder heat transfer

Jizu LV, Minli BAI, Long ZHOU, Jian ZHOU,

《能源前沿（英文）》 2010年 第4卷 第3期   页码 392-401 doi: 10.1007/s11708-009-0066-1

摘要： Combustion chamber components (cylinder head-cylinder liner-piston assembly-oil film) were treated as a coupled body. Based on the three-dimensional numerical simulation of the heat transfer of the coupled body, a coupled three-dimensional calculation model for the in-cylinder working process and the combustion chamber components was built with domain decomposition and boundary coupling method, which adopts the coupled three-dimensional simulation of in-cylinder working process and the combustion chamber components. The model was applied in the investigation of the influence of space non-uniformity in heat transfer among combustion chamber components on in-cylinder heat transfer. The results show that the effect of wall temperature space non-uniform distribution of combustion chamber components on heat transfer happens mainly at the end of the compression stroke and expansion stroke. Therefore, it can be concluded that wall temperature space non-uniform distribution of combustion chamber components would influence heat transfer during the intake and exhaust stroke obviously.

关键词： heat transfer     space non-uniformity     soot emission     in-cylinder     diesel    

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Low temperature synthesis of visible light responsive rutile TiO

John TELLAM, Xu ZONG, Lianzhou WANG

《化学科学与工程前沿（英文）》 2012年 第6卷 第1期   页码 53-57 doi: 10.1007/s11705-011-1165-1

摘要： A nano-structured TiO with rutile phase was synthesized by using the hydrothermal method from a titanium carbide (TiC) nano-powder precursor at low temperature to produce a stable visible light responsive photocatalyst. The rutile phase was formed at temperature as low as 100°C, and both synthesis time and temperature affected its formation. The rutile particles showed a faceted nano-rod structure, and were tested for absorption and photo-degradation ability under visible light. Particles with shorter synthesis times showed higher visible light absorption and corresponding photo-degradation ability, while those synthesized at lower temperatures had lower, but still evident, degradation ability under visible light.

关键词： photocatalysis     rutile     TiO2     hydrothermal     visible     titanium carbide    

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NiBO (B = Mn or Co) catalysts for NH-SCR of NO at low-temperature in microwave field

《环境科学与工程前沿（英文）》 2023年 第17卷 第8期 doi: 10.1007/s11783-023-1696-y

摘要：

● Microwave-assisted catalytic NH3-SCR reaction over spinel oxides is carried out.

关键词： Microwave field     Spinel oxides     NOx     Selective catalytic reduction    

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Potassium carbonate-based ternary transition temperature mixture (deep eutectic analogues) for CO absorption

《环境科学与工程前沿（英文）》 2022年 第16卷 第7期 doi: 10.1007/s11783-021-1500-9

摘要：

•Addition of hindered amine increased thermal stability and viscosity of TTTM.

关键词： Ternary transition-temperature mixture     FT-IR and thermal stability analysis     Viscosity and correlation study     Eyring’s absolute rate theory     CO2 solubility     Density functional theory (DFT).    

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Metal-organic framework loaded manganese oxides as efficient catalysts for low-temperature selective

Minhua Zhang, Baojuan Huang, Haoxi Jiang, Yifei Chen

《化学科学与工程前沿（英文）》 2017年 第11卷 第4期   页码 594-602 doi: 10.1007/s11705-017-1668-5

摘要： A mild deposition method was used to fabricate Mn-based catalysts on a UiO-66 carrier for the selective catalytic reduction of NO by NH (NH -SCR). The catalyst with 8.5 wt-% MnO loading had the highest catalytic activity for NH -SCR with a wide temperature window (100–290 °C) for 90% NO conversion. Characterization of the prepared MnO /UiO-66 catalysts showed that the catalysts had the crystal structure and porosity of the UiO-66 carrier and that the manganese particles were well-distributed on the surface of the catalyst. X-ray photoelectron spectroscopy analysis showed that there are strong interactions between the MnO and the Zr oxide secondary building units of the UiO-66 which has a positive effect on the catalytic activity. The 8.5 wt-% MnO catalyst maintained excellent activity during a 24-h stability test and exhibited good resistance to SO poisoning.

关键词： metal-organic framework     selective catalytic reduction     manganese oxides     deNOx     SO2 resistance    

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Laboratory study on high-temperature adsorption of HCl by dry-injection of Ca(OH)

Junjun TAN,Guohua YANG,Jingqiao MAO,Huichao DAI

《环境科学与工程前沿（英文）》 2014年 第8卷 第6期   页码 863-870 doi: 10.1007/s11783-013-0618-9

摘要： Combustion-generated hydrogen chloride (HCl) is considered to be a very hazardous acid gaseous pollutant. This paper presents a laboratory study on the dry adsorption of HCl. The experiments were conducted in a dual-layer granular bed filter, at gas temperatures of 500°C–700°C and (Ca)/ (Cl)molar ratios of 1.0–5.0 using the silver nitrate titration method by dry adsorbent powders Ca(OH) . Mainly, the adsorption efficiency of HCl and utilization efficiency of Calcium were studied, by varying relevant factors including (Ca)/ (Cl), temperature, feeding method, water vapor and CO . With a relatively higher HCl concentration of 1000 ppm, the experimental results revealed that 600°C may be the optimum temperature for HCl adsorption when optimum (Ca)/ (Cl) was 2.5 in our tests. The results also demonstrated that the feeding at a constant pressure was more effective, and the HCl adsorption efficiency could rapidly reach over 90% with (Ca)/ (Cl) = 2.5 at 600°C. Furthermore, the HCl adsorption efficiency was found to be slightly promoted by water vapor, while could be impeded by CO , and the utilization efficiency of calcium could be up to 74.4% without CO , while was only 36.8% with CO when (Ca)/ (Cl) was 2.5 at 600°C.

关键词： acid gas HCl     Ca(OH)2     dry adsorption     high temperature     dual-layer granular bed filter    

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Promotion of transition metal oxides on the NH

Weiman Li, Haidi Liu, Yunfa Chen

《环境科学与工程前沿（英文）》 2017年 第11卷 第2期 doi: 10.1007/s11783-017-0914-x

摘要： Manganese and chromium oxides promote the NH -SCR activity of Zr-Ce mixed oxide. Cr-Zr-Ce mixed oxide exhibited>80% NO conversion at a wide temperature window. More acid sites and higher reducibility may responsible for the high SCR ability. Chromium oxide and manganese oxide promoted ZrO -CeO catalysts were prepared by a homogeneous precipitation method for the selective catalytic reduction of NO with NH . A series of characterization including X-ray diffraction (XRD), high-resolution transmission electron microscope (HR-TEM), Brunauer–Emmett–Teller (BET) surface area analysis, H temperature-programmed reduction (H -TPR), and X-ray photoelectron spectroscopy (XPS) were used to evaluate the influence of the physicochemical properties on NH -SCR activity. Cr-Zr-Ce and Mn-Zr-Ce catalysts are much more active than ZrO -CeO binary oxide for the low temperature NH -SCR, mainly because of the high specific surface area, more surface oxygen species, improved reducibility derived from synergistic effect among different elements. Mn-Zr-Ce catalyst exhibited high tolerance to SO and H O. Cr-Zr-Ce mixed oxide exhibited>80% NO conversion at a wide temperature window of 100°C–300°C. DRIFT studies showed that the addition of Cr is beneficial to the formation of Bronsted acid sites and prevents the formation of stable nitrate species because of the presence of Cr . The present mixed oxide can be a candidate for the low temperature abatement of NO .

关键词： NH3-selective catalytic reduction     NOx     Low temperature     Cr-Zr-Ce    

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Regeneration of Fe

Ruizhuang ZHAO, Ju SHANGGUAN, Yanru LOU, Jin SONG, Jie MI, Huiling FAN

《化学科学与工程前沿（英文）》 2010年 第4卷 第4期   页码 423-428 doi: 10.1007/s11705-010-0503-z

摘要： Regeneration of a high-temperature coal gas desulfurization sorbent is a key technology in its industrial applications. A Fe O -based high-temperature coal gas desulfurizer was prepared using red mud from steel factory. The influences of regeneration temperature, space velocity and regeneration gas concentration in SO atmosphere on regeneration performances of the desulfurization sorbent were tested in a fixed bed reactor. The changes of phase and the composition of the Fe O -based high-temperature coal gas desulfurization sorbent before and after regeneration were examined by X-ray diffraction(XRD) and X-ray Photoelectron spectroscopy(XPS), and the changes of pore structure were characterized by the mercury intrusion method. The results show that the major products are Fe O and elemental sulfur; the influences of regeneration temperature, space velocity and SO concentration in inlet on regeneration performances and the changes of pore structure of the desulfurization sorbent before and after regeneration are visible. The desulfurization sorbent cannot be regenerated at 500°C in SO atmosphere. Within the range of 600°C – 800°C, the time of regeneration becomes shorter, and the regeneration conversion increases as the temperature rises. The time of regeneration also becomes shorter, and the elemental sulfur content of tail gas increases as the SO concentration in inlet is increased. The increase in space velocity enhances the reactive course; the best VSP is 6000 h for regeneration conversion. At 800°C, 20 vol-% SO and 6000 h , the regeneration conversion can reach nearly to 90%.

关键词： high-temperature coal gas     Fe2O3 desulfurization sorbent     SO2 atmosphere     regeneration behaviors     sulfur recovery    

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标题 作者 时间 类型 操作

Design and analysis of electrothermal metasurfaces

Xiu LIU, Zhuo LI, Zexiao WANG, Hyeong Seok YUN, Sheng SHEN

期刊论文

CeO doping boosted low-temperature NH-SCR activity of FeTiO catalyst: A microstructure analysis and reaction

期刊论文

Modeling and optimization of an enhanced battery thermal management system in electric vehicles

Mao LI, Yuanzhi LIU, Xiaobang WANG, Jie ZHANG

期刊论文

Cu-modified active carbon fiber significantly promoted HS and PH simultaneous removal at a low reaction temperature

期刊论文

Preparation of Cu/ZnO/Al

Hui FAN, Huayan ZHENG, Zhong LI

期刊论文

Denitrification performance and sulfur resistance mechanism of Sm–Mn catalyst for low temperature NH-SCR

期刊论文

Wide gap active brazing of ceramic-to-metal-joints for high temperature applications

K. Bobzin,L. Zhao,N. Kopp,S. Samadian Anavar

期刊论文

Effect of heat transfer space non-uniformity of combustion chamber components on in-cylinder heat transfer

Jizu LV, Minli BAI, Long ZHOU, Jian ZHOU,

期刊论文

Low temperature synthesis of visible light responsive rutile TiO

John TELLAM, Xu ZONG, Lianzhou WANG

期刊论文

NiBO (B = Mn or Co) catalysts for NH-SCR of NO at low-temperature in microwave field

期刊论文

Potassium carbonate-based ternary transition temperature mixture (deep eutectic analogues) for CO absorption

期刊论文

Metal-organic framework loaded manganese oxides as efficient catalysts for low-temperature selective

Minhua Zhang, Baojuan Huang, Haoxi Jiang, Yifei Chen

期刊论文

Laboratory study on high-temperature adsorption of HCl by dry-injection of Ca(OH)

Junjun TAN,Guohua YANG,Jingqiao MAO,Huichao DAI

期刊论文

Promotion of transition metal oxides on the NH

Weiman Li, Haidi Liu, Yunfa Chen

期刊论文

Regeneration of Fe

Ruizhuang ZHAO, Ju SHANGGUAN, Yanru LOU, Jin SONG, Jie MI, Huiling FAN

期刊论文